It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. Wet hydrogen sulfide h2s cracking inspectioneering. Nickelchromiummolybdenum alloy hastelloy c2000 specialty. Mechanism of sulfide corrosion hydrogen sulfide corrosion can occur by two mechanisms. Hydrogen sulfide is a chemical compound with the formula h 2 s, and is often a colorless gas with a rotten egg odor, commonly referred to as sewer gas. The effect of hydrogen sulfide h 2 s on the corrosion behavior of commercially pure aluminum din al 99. The effect of low h2s concentrations on welded steels march. Corrosionpedia what is sulfide stress cracking ssc. Stress corrosion cracking the international institute of. In stress corrosion cracking, its first cousin, the corrosion process, generally pitting, must start to get the hydrogen generation started. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in highstrength steels and in localized hard zones in weldment of susceptible.
High temperature hydrogen sulfide corrosion of carbon steel and low chrome alloys has become a serious problem in the petroleum industry in connection with the increasing use of high pressure hydrogenation and dehydrogenation processes for upgrading petroleum fractions. Protect aluminum from hydrogen sulfide with nickel plating or electroless nickel offers additional detail on a very similar subject. Hydrogen stress cracking is a form of hydrogen embrittlement that occurs when corrosion from acids like wet hydrogen sulfide and hydrofluoric acid cause atomic hydrogen to penetrate hardened or higher strength steels and cause stress cracking. Hydrogen sulfide stress corrosion cracking in materials. The major hazards of h 2 s are its ability to cause rapid damage to health or sudden death due to accidental exposure and metal integrity failure due to general corrosion or cracking. Stress corrosion cracking an overview sciencedirect topics. Jun 27, 2017 this video is a demonstration of stress corrosion on an aisi 4340 steel sample.
If the presence of hydrogen sulphide causes entry of hydrogen into the component, the cracking phenomenon is often termed sulphide stress cracking ssc. There are several types of stress corrosion cracking scc, for example, chlorideinduced scc and h 2 sinduced scc. Nickelchromiummolybdenum alloy hastelloy c2000 specialty among nickel alloys by alloy environmentally assisted cracking or eac refers to the attacks including stress corrosion cracking scc, hydrogen embrittlement he, sulfide stress cracking ssc, liquid metal embrittlement lme and corrosion fatigue cf. The effect of low h2s concentrations on welded steels. Mild steel is a popular structural steel in this industry but is susceptible to surface scale formation and associated corrosive action, the prevention of which requires some. It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. High temperature hydrogen sulfide corrosion corrosion. From the chemical composition point of view, corrosion resistant nickel based alloys are categorized as pure nickel, nickelcopper alloys, nickelmolybdenum alloys, nicrmo alloys and nicrfemo alloys. Detection, control, and correction of hydrogen sulfide. Thermal spray inert hvof coatings inside amine towers, condensers, channels and separators in california, usa. The 7046t4 alznmg alloy has been chosen for this study because its low corrosion susceptibility allows hydrogen embrittlement he to be more easily distinguished during scc tests.
Corrosion of metal and concrete is a major issue associated with the generation and oxidation of hydrogen sulfide. Although hydrogeninduced cracking and stress corrosion cracking are similar phenomena, both types of damage are usually described and treated separately. Sulfide stress cracking an overview sciencedirect topics. Wet h 2 s cracking can occur in susceptible steels exposed to aqueous environments containing hydrogen sulfide. Hydrogen diffuses along the grain boundaries and combines with the carbon, which is alloyed with the iron, to form methane gas. Oxidation of hydrogen sulfide and corrosion of stainless. Sulfide stress cracking is a form of hydrogen embrittlement that occurs in highstrength steels and in localized hard zones in weldment of susceptible materials.
It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Sulfide stress cracking is the cracking of a metal under the combined action of tensile stress and corrosion in the presence of water and hydrogen sulfide a form of hydrogen stress cracking. A corrosive medium especially chloridebearing or hydrogen sulphide h 2 s media. Sulfide stress cracking is also environmentally produced so you have a delay until the sulfide environment causes hydrogen entry into the metal. This type of failure is known as stress corrosion cracking, often abbreviated to scc. Effect of carbon migration on sulfide stress corrosion. The results indicate that flow control valve body failed due to combination of hydrogen induced corrosion cracking hicc and sulfide stress corrosion cracking sscc. This penetration can lead to the brittle fracture of materials that are normally ductile when hydrogen happens to be present in their environment. Resistance to corrosion and stress corrosion cracking in hydrogen sulphide environments scanning electron microscopy of cunimnalnb, carried out after exposure in acidified hydrogen sulphide solution at room temperature, reveals that the aluminium content of the material produces an oxide layer which gives the alloy a considerable degree of. Stress corrosion cracking behavior of nickel base alloys. The resistance to chlorideinduced stress corrosion cracking of uns n08031 was tested on ubend specimens according to astm g 30 for a testing time of 2000 hours. In this paper, mechanical performance test, slow strain rate test ssrt and optical microscopy analysis were employed in studying the effect of carbon migration on sulfide stress corrosion cracking sscc behaviors of cr5moa3020cr18ni9 dissimilar joints. The effects of hydrogen during stress corrosion cracking mechanisms scc have been highlighted for many years but hydrogen trapping mechanisms are not yet well understood for 7xxx aluminium alloys.
An increase in the partial pressure of hydrogen sulfide aggravates the catastrophic breakdown of carbon steel, yet diminishes both the corrosion rate and the localization of corrosion attack on aluminum alloys. Alloys which are commercially available and those which have modified metallurgical structures and. If the presence of hydrogen sulfide causes entry of hydrogen into the component, the cracking phenomenon is often termed sulphide stress cracking ssc c. The blistering damage tends to form parallel to the. Sulphide stress cracking ssc is the biggest concern 9. It is a form of hydrogenrelated cracking and can have two distinct morphologies. Hydrogen embrittlement also known as hydrogen assisted cracking and hydrogeninduced cracking, describes the embrittling of metal after being exposed to hydrogen. Link to corrigendum together with my colleagues and good friends dr.
Aluminum alloys that contain appreciable amounts of soluble alloying elements, primarily copper, magnesium, silicon, and zinc, are susceptible to stress corrosion cracking scc. Environmental cracking of stainless and nibase alloys hydrogen sulfide corrosion acidic environments. Zaki ahmad, in principles of corrosion engineering and corrosion control, 2006. The composition of volatile and solid products of oxidation of hydrogen sulfide and stainless steel in gas mixtures containing h2s, o2, h2o, and co2 has been determined using mass spectrometry, xray diffraction analysis, and scanning electron microscopy. Aluminum corrosion an overview sciencedirect topics.
According to hic and ssc laboratory tests and also with regard to cost of engineering materials, it was evident that the best alternative for the valve body alloy is a217 wc9. Corrosion behavior of aluminum alloys in the presence of. Wet h 2 s corrosion can be a particularly dangerous form of corrosion because damage caused by it takes place on the interior of. Materials and corrosion trends in offshore and subsea oil and. It is generally recognised that the risk of sulphide stress corrosion cracking in ferritic steels increases with hardness, and maximum hardness limits are the basis of guidelines for avoidance of cracking in many standards. The corrosionelectrochemical behavior of both carbon steel and aluminum alloys in hydrogen sulfidebearing mineralized media is considered. To check its resistance to scc and ssc, several tests were performed. Hvaf equipment and coating services to protect chemical, oil and gas refinery pressure vessels from h.
Hydrogen sulfide stress corrosion cracking in materials for. There are maximum acceptable h 2 s concentration limits in sale quality oil and gas, which require. In the aggressive marine environment even the more resistant alloys may be affected by hydrogeninduced cracking, or by chloride or sulphide stress corrosion. Sulphide stress corrosion cracking sscc laboratory. In that article, we concluded that while localized corrosion appears to be a prerequisite for anodic eac modes such as stress corrosion cracking scc, hydrogen assisted eac mechanisms like hydrogen stress cracking hsc are exacerbated at cathodic potentials. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small. Sulfide stress cracking is a function of hydrogen sulfide concentration as low as ppm, hydrogen sulfide partial pressure, stresses, material yield strength, temperature and ph. Stress corrosion cracking international institute of.
Temperature the concentration of chloride increases with increasing temperatures, while the effect of hydrogen decreases owing to its increased mobility in the ferrite matrix. Hydrogen can assist in the propagation of corrosion fatigue cracks and can also cause sulphide stress corrosion cracking in ferritic and martensitic steels, including the. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. Pdf hydrogen sulfide stress corrosion cracking of high. The incubation time for crevice corrosion and pitting in seawater is relatively short, often only a few days. From the extensive weightloss studies conducted around the world on aluminum corrosion rates of 0. Hydrogen sulfide corrosion and its prevention is an important topic in a range of industrial processes and environments including oil and gas and its related activities. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature.
About the role of hydrogen in stress corrosion cracking of. Hydrogen sulfide attack and corrosion of copper electrical. Dense metal h2s resistant vessel coating to mitigate sour gas acid corrosion. Hydrogen sulphide cracking is one of the important processes in the oil and gas industry as the hydrocarbons that are produced contain considerable amounts of hydrogen sulphide. Jul 25, 2017 materials and corrosion trends in offshore and subsea oil and gas production. The first type is commonly referred to as hydrogen induced cracking hic and can occur where little or no applied or residual tensile stress exists. It has been shown that holding an h2so2 mixture at 301 k results in prevailing formation of elemental sulfur and iron sulfides in the.
Hydrogen sulfide stress corrosion cracking of high strength steel wire article pdf available in corrosion houston tx 282. Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. Jun 03, 2018 hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. In this situation, cracking failures can often be thought of as a type of stress corrosion cracking. Hydrogen induced cracking hic is a form of tiny blistering damage caused by a high concentration of hydrogen in steel.
Impermeable alloyed coating to protect petrochemical. Stress corrosion cracking facts and how to reduce the risk. Hydrogen sulfide is a colorless, very poisonous, flammable gas with the characteristic foul odor of rotten eggs. Sulphide stress corrosion cracking sulphide stress cracking sscc has special importance in gas and oil industry, as the materials being processed there natural gas and crude oil often contain considerable amount of hydrogen sulphide. The manuscript can be downloaded following this link or directly. This is a type of deterioration which can be linked to corrosion and corrosion control processes. It is now well known that ssc is a particular form of hydrogen stress cracking. Corrosion inhibitors for systems with a high content of hydrogen sulphide h2s in the produced fluids since the discovery and development of oil and gas fields containing hydrogen sulfide in the production wells, the problem of protection of metal from the hydrogen sulfide corrosion arose acutely. In the case of a crystal lattice becoming saturated or coming into contact with atomic hydrogen, many alloys and metals may. The role of hydrogen in the mechanism of stress corrosion cracking has been known since the 1970s so that preventative measures have since been introduced.
Ssc is a form of spontaneous brittle breakdown in occurring in highstrength. Paper 143, corrosion 2000, nace international, orlando, florida, usa, 2631 march 2000. When they are processed in the refineries, hydrogen sulphide gas h 2 s, which is a toxic gas is produced. Sulfide stress cracking of nickelcontaining lowalloy steels. This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes. Jan 08, 2002 hydrogen sulfide, chloride and ph are the principal agents of sulfide stress corrosion cracking. The incubation time for stress corrosion cracking can be very short, sometimes measured in hours. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. S resistant coating to protect pressure vessels from. Stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly along grain boundaries. An extensive failure analysis shows how many service failures occurred in the industry and what kind of alloys and stresses led to initiation and propagation of stress corrosion cracks which caused these service failures.
Aluminum alloys most often associated with stresscorrosion cracking in actual service are 2014, 2024, 2219, 7075, 7079, and 7178 alloys, and cast alloys of ternalloy 7, 40e, 195, and 220 compositions. The observed crack propaga tion is the result of the combined and synergistic interaction of mechanical stress and corrosion re actions. It involves atomic hydrogen, which is the smallest atom, that diffuses into a metallic structure. Sulfide stress cracking is the worst type of corrosion in the presence of hydrogen sulfide.
Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. The corrosion electrochemical behavior of both carbon steel and aluminum alloys in hydrogen sulfidebearing mineralized media is considered. Pdf hydrogen sulfide corrosion of carbon and stainless. If the presence of hydrogen sulfide causes entry of hydrogen into the component, the cracking phenomenon is often termed sulphide stress cracking ssc the use of cathodic protection for corrosion protection if the process is not properly. Material considerations when working with hydrogen 3. High levels of stress in service, or residual stress from manufacturing may result in selective corrosion of more highly stressed regions of an otherwise corrosion resistant structure.
Corrosionpedia what is hydrogeninduced cracking hic. The corrosivity of a location would depend upon the distance the airborne salt travels, the direction and velocity of the wind. We published this article under an openaccess license. The stress corrosion cracking behaviour of uns n08031 in. Effect of hydrogen sulfide on aqueous corrosion of. The most common forms of wet h 2 s cracking are hydrogen induced cracking hic, stress oriented hydrogen induced cracking sohic, and sulfide stress cracking ssc.
The study of stress corrosion was supported by the office of navel research. Aluminum alloys that contain appreciable amounts of soluble alloying elements, primarily copper, magnesium, silicon, and zinc, are susceptible to stresscorrosion cracking scc. Sulfide stress cracking mostly occurs in very highly acidic environments. Damage due to hydrogen embrittlement and stress corrosion.
Hydrogen sulphide these corrosion data are mainly based on results of general corrosion laboratory tests, carried out with pure chemicals and water solutions nearly saturated with air the corrosion rate can be quite different if the solution is free from oxygen. In a previous post, we discussed the broad differences between anodic and cathodic forms of environmentally assisted cracking eac. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis. Sulfide stress corrosion cracking and hydrogen induced. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. Pdf sulfide stress corrosion cracking and hydrogen.
One is to perform a stress relieving treatment on the metal to reduce hardness levels to acceptable levels in an annealed microstructure. Protection of metal from the hydrogen sulfide corrosion. It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Several mitigation methods are known to prevent sulfide stress cracking and hydrogen induced corrosion. Although hydrogen induced cracking and stress corrosion cracking are similar phenomena, both types of damage are usually described and treated separately. Stress corrosion cracking scc or called as environmentally assisted cracking eac may take place at the electrochemical potential range.